Genesis 19:24

Then the LORD rained brimstone and fire on Sodom and Gomorrah, from the LORD out of the heavens.

Surrounding context

19:23 The sun had risen upon the earth when Lot entered Zoar.

19:24 Then the LORD rained brimstone and fire on Sodom and Gomorrah, from the LORD out of the heavens.

19:25 So He overthrew those cities, all the plain, all the inhabitants of the cities, and what grew on the ground.